Ammonioalunite is a rare sulfate mineral found primarily in geothermal environments where ammonia-rich fluids interact with aluminous rocks. It typically appears as white, earthy, or powdery crusts associated with fumaroles and solfataras. Collectors primarily seek this mineral for its distinct chemical composition within the alunite supergroup.

Hardness
2-3
Mohs
Luster
Vitreous
Streak
White
Transparency
Semitransparent

Is this ammonioalunite?

5-step field check

Run through these checks against the specimen in your hand. The more boxes tick, the more confident the ID.

  • 1
    Test the hardness
    Try to scratch ammonioalunite with a known reference. Ammonioalunite sits at Mohs 2-3, softer than the next harder reference, harder than the previous one.
  • 2
    Check the streak
    Drag the specimen across an unglazed porcelain plate. Streak: white.
  • 3
    Read the luster
    Hold the specimen under a strong light. Luster: vitreous.
  • 4
    Match the color range
    Compare against the expected color range: white, gray white.
  • 5
    Look at form & habit
    Crystal system: trigonal. Typical habit: efflorescences, massive, rhombohedral crystals.

Often confused with

Ammonioalunite vs. its common look-alikes, and how to tell them apart in the field.

Often found alongside ammonioalunite

Minerals reported to co-occur with ammonioalunite. Spotting these in float or country rock is a strong cue you are in the right ground.

All properties

Chemical formula
(NH₄)Al₃(SO₄)₂(OH)₆
Mohs hardness
2-3
Density
2.4 g/cm³
Streak
White
Luster
Vitreous
Transparency
Semitransparent
Crystal system
Trigonal
Crystal habit
Efflorescences, massive, rhombohedral crystals
Cleavage
On [{0001}, perfect.] (by analogy with the alunite group)
Rarity
Rare
Uses
Collector, Research
Host rock
Formed in hot springs under very acid conditions, rich in ammonium and sulfate, poor in potassium, below 100°C

Where rockhounds find ammonioalunite

Classic worldwide localities

  • Geysers, Sonoma Co., California, USA

Field-hunting tip

Where it forms: Formed in hot springs under very acid conditions, rich in ammonium and sulfate, poor in potassium, below 100°C. If you start seeing ammoniojarosite in float, you are in the right ground. Typical habit: efflorescences, massive, rhombohedral crystals. Train your eye for that shape before scanning the outcrop.

Common questions

How do you identify ammonioalunite?+
Mohs hardness is 2-3. Luster: vitreous. The streak is white. Common colors include white, gray white.
Where is ammonioalunite found?+
Notable localities include Geysers, Sonoma Co., California, USA.
What rocks look like ammonioalunite?+
Ammonioalunite is most often confused with Alunite, Natroalunite. A quick hardness test and a streak check separate the look-alikes faster than color alone.
What minerals are found with ammonioalunite?+
Ammonioalunite commonly co-occurs with Ammoniojarosite. Spotting any of these in float or country rock is a useful trip signal.
What kind of rock does ammonioalunite form in?+
Where it forms: Formed in hot springs under very acid conditions, rich in ammonium and sulfate, poor in potassium, below 100°C. Working float back to the host body is the standard way to chase a fresh occurrence.
What is ammonioalunite used for?+
Ammonioalunite is used in collector, research.

Find ammonioalunite on the map

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